2,5-Dichloro-N-(3-methylphenyl)benzenesulfonamide

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2,5-Dichloro-N-(3-methyl­phen­yl)benzenesulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the dihedral angle between the aromatic rings is 76.62 (10)° and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle = -51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops.

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2,2-Dichloro-N-(3-nitro­phen­yl)acetamide

The conformation of the N-H bond in the structure of the title compound (3NPDCA), C(8)H(6)Cl(2)N(2)O(3), is anti to the meta-nitro group, similar to that in the structures of 2-chloro-N-(3-nitro-phen-yl)acetamide (3NPCA) and 2,2,2-trichloro-N-(3-nitro-phen-yl)acetamide (3NPTCA), and the meta-chloro group in 2,2-dichloro-N-(3-chloro-phen-yl)acetamide (3CPDCA). The geometric parameters of 3NPDCA ...

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2,4-Dichloro-N-(3-chloro­phen­yl)benzene­sulfonamide

In the title compound, C(12)H(8)Cl(3)NO(2)S, the conformation of the N-H bond in the C-SO(2)-NH-C segment is anti to the meta-Cl in the aniline ring. The mol-ecule is twisted at the S atom, the C-SO(2)-NH-C torsion angle being 62.3 (2)°. The dihedral angle between the two benzene rings is 69.3 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.

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2,4-Dichloro-N-(3-methyl­phen­yl)benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bonds in the C-SO(2)-NH-C segments have gauche torsions with respect to the S=O bonds. The dihedral angle between the two benzene rings is 68.6 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.

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3,5-Dichloro-N-(2-methyl­but-3-yn-2-yl)benzamide

In the title compound, C(12)H(11)Cl(2)NO, the amide group is twisted by a dihedral angle of 31.98 (2)° with respect to the benzene ring. In the crystal structure, mol-ecules are linked via N-H⋯O hydrogen bonds, forming one-dimensional supra-molecular chains.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812032023